Cannabicyclolic acid (CBLA)
Molecular Formula: C22H30O4
Image credit: Wikimedia Commons
CBLA was first isolated by Shoyama et al. (1972).
CBLA is not an original cannabinoid but an artificial product, converted from cannabichromenic acid(CBCA) by natural irradiation during the storage of the Cannabis.
Cannabis. VI. Cannabicyclolic acid.
Shoyama, Y., Oku, R., Yamauchi, T., Nishioka, I.,
Chemical and Pharmaceutical Bulletin 20 (9), 1927 – 1930.
http://doi.org/10.1248/cpb.20.1927